Analysis of benzoic acid and sorbic acid in Thai rice wines and distillates by solid-phase sorbent extraction and high-performance liquid chromatography

نویسندگان

  • Ittipon Techakriengkrai
  • Ranee Surakarnkul
چکیده

An application of solid-phase extraction (SPE) for high-performance liquid chromatography (HPLC) analysis was developed for the rapid determination of benzoic acid and sorbic acid in Thai rice wine and distillate products. The SPE extraction gave promising results with 95.7+1.7% recovery for benzoic acid standard, and 95.2+2.3% for sorbic acid standard. Mean relative standard deviation (RSD) for both acids was 1.99%. Percentage recoveries when spiked in real samples were 92.6+1.2% and 93.7+1.7% for benzoic acid and sorbic acid in rice wine, and 92.7+1.2% and 92.5+1.8% in distillate, respectively. Detection limits were 0.2mg/L for benzoic acid and 0.1mg/L for sorbic acid. The overall experimental time for each sample was 15min with 1.56% RSD. Results show that all detected data were below the maximum permitted concentration by the Joint FAO/WHO Expert Committee on Food Additives (JECFA). Results showed a broad range between products from different areas, explained by principal component analysis (PCA) models. This SPE-HPLC technique was proved to be rapid, accurate, and precise for the analysis of benzoic and sorbic acid in alcoholic beverages. r 2006 Elsevier Inc. All rights reserved.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Preconcentration and Determination of Mefenamic Acid in Pharmaceutical and Biological Fluid Samples by Polymer-grafted Silica Gel Solid-phase Extraction Following High Performance Liquid Chromatography

Abstract Mefenamic acid is a nonsteroidal anti-inflammatory drug (NSAID) that has analgesic,anti-infammatory and antipyretic actions. It is used to relieve mild to moderate pains. Solid-phase extraction of mefenamic acid by a polymer grafted to silica gel is reported . Poly allyl glycidyl ether/iminodiacetic acid-co-N, N-dimethylacrylamide was synthesized and grafted to silica gel and was used ...

متن کامل

Preconcentration and Determination of Mefenamic Acid in Pharmaceutical and Biological Fluid Samples by Polymer-grafted Silica Gel Solid-phase Extraction Following High Performance Liquid Chromatography

Abstract Mefenamic acid is a nonsteroidal anti-inflammatory drug (NSAID) that has analgesic,anti-infammatory and antipyretic actions. It is used to relieve mild to moderate pains. Solid-phase extraction of mefenamic acid by a polymer grafted to silica gel is reported . Poly allyl glycidyl ether/iminodiacetic acid-co-N, N-dimethylacrylamide was synthesized and grafted to silica gel and was used ...

متن کامل

Polyaniline/Graphene Nanocomposite as a Promising Sorbent for Dispersive Solid Phase Extraction of Avermectins from Citrus Fruit Juice

A solid phase extraction sorbent based on polyaniline/graphene nanocomposite is presented. The structure and morphology of synthesized nanocomposite were investigated by Fourier transform infrared spectroscopy, field emission scanning electron microscopy, X-ray diffraction and thermal gravimetric analysis. The dispersive solid phase extraction was employed to the isolation and preconcentration ...

متن کامل

Chemically Modified Eggshell Membrane as an Adsorbent for Solid-Phase-Extraction of Morphine Followed by High Performance Liquid Chromatography Analysis

In this project, eggshell membrane was used as a solid phase extraction sorbent for extraction of morphine followed by HPLC analysis. At first, raw eggshell membrane was used and then, because of low adsorption of morphine on untreated eggshell membrane (<70%), modification of eggshell membrane surface was carried out using different surfactants and amines. The amine modified eggshells characte...

متن کامل

Selective Liquid-Liquid Extraction of Lead Ions Using Newly Synthesized Extractant 2-(Dibutylcarbamoyl)benzoic Acid

A new carboxylic acid extractant, named 2-(dibutylcarbamoyl)benzoic acid, is prepared and its potential for selective solvent extraction and recovery of lead ions from industrial samples was investigated. The slope analysis indicated that the lead ions are extracted by formation of 1:2 metal to ligand complexes. The effect of the parameters influencing the extraction efficiency including kind o...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:

دوره   شماره 

صفحات  -

تاریخ انتشار 2007